| Preface |
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ix | |
| Introduction |
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xi | |
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Preparation of phosphoric anhydride |
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1 | (4) |
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Structure and physico-chemical properties of phosphoric anhydride |
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5 | (16) |
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5 | (1) |
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Molecular formula of phosphoric anhydride |
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6 | (1) |
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Electron diffraction and X-ray studies |
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7 | (6) |
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13 | (1) |
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Thermodynamic parameters of phosphoric anhydride |
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14 | (1) |
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Spectroscopic methods of study |
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15 | (6) |
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Reactivity of phosphoric anhydride |
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21 | (142) |
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Reactions of phosphoric anhydride with oxygen-containing compounds |
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21 | (39) |
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Hydration of phosphoric anhydride |
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21 | (8) |
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Reactions with alcohols and phenols |
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29 | (19) |
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48 | (7) |
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55 | (3) |
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Reactions with orthoesters |
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58 | (1) |
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59 | (1) |
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Reaction with acetic anhydride |
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60 | (1) |
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60 | (1) |
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Reactions of phosphoric anhydride with nitrogen-containing compounds |
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61 | (36) |
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61 | (1) |
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62 | (3) |
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Reactions of acyclic amides and thioamides |
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65 | (1) |
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Reactions with benzoylamides and thiobenzoylamides |
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66 | (1) |
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Reactions with acetanilides |
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67 | (7) |
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Reactions with benzanilides |
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74 | (12) |
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Reactions with cyclic amides and thioamides |
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86 | (1) |
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Reactions with five-membered cyclic amides |
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86 | (2) |
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Reactions with 1,3-pyrimidine-2,4,6-triones |
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88 | (1) |
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Reactions with 1,3-pyrimidine-2-thione-4,6-dione |
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89 | (2) |
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Reactions with hydrazide of benzoic acid |
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91 | (1) |
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91 | (4) |
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Reactions with o-diaminobenzenes |
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95 | (2) |
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Reactions of phosphoric anhydride with phosphorus-containing compounds |
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97 | (3) |
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Reactions of phosphoric anhydride with arenes and C--H nucleophiles |
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100 | (1) |
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Reactions of phosphoric anhydride with silicon-containing compounds |
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101 | (9) |
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Reactions of phosphoric anhydride with organometallic compounds |
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110 | (2) |
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Elimination, condensation and rearrangement reactions promoted by phosphoric anhydride |
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112 | (51) |
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112 | (29) |
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141 | (11) |
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Other elimination reactions |
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152 | (1) |
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Condensation, rearrangement and substitution |
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152 | (11) |
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Phosphoric anhydride in the evolution of life on the Primitive Earth |
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163 | (4) |
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Phosphoric anhydride and its derivatives in biological chemistry |
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167 | (20) |
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Applications of phosphoric anhydride |
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187 | (32) |
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Environmental applications |
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187 | (2) |
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Ionites with the phosphate group |
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187 | (1) |
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Water conditioning and controlling |
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188 | (1) |
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189 | (2) |
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Preparation and application of inorganic compounds derived from phosphoric anhydride |
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191 | (10) |
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Ortho phosphoric acid and inorganic phosphates |
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191 | (1) |
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Reactions with hydrogen peroxide and oxygen: peroxyphosphoric acids |
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192 | (1) |
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Reactions with halogen compounds, nitrogen oxides and oxyacids |
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193 | (3) |
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Reaction with metal oxides, hydroxides, carbonates, sulphates and nitrides |
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196 | (2) |
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Ligand modification via dehydration |
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198 | (2) |
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Dehydration of inorganic hydrates |
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200 | (1) |
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Industrial inorganic applications of phosphoric anhydride |
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200 | (1) |
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Application of organic phosphates derived from phosphoric anhydride |
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201 | (18) |
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Surfactants, detergents and related applications |
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202 | (6) |
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208 | (3) |
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Emulsifiers, lubricants and antiwear additives |
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211 | (1) |
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212 | (3) |
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Insecticides, fungicides, extractants and other applications |
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215 | (3) |
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Handling, health and safety |
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218 | (1) |
| References |
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219 | (26) |
| Index |
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245 | |
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